E-mail this image
Leonardo DiCaprio and Gisele Bundchen
Martin Scorsese go-to boy Leonardo DiCaprio and and the leggy Brazilian supermodel were a couple on-and-off for three years before calling it quits for good in 2005. Most reports attribute this to Bundchen being ready to settle down while DiCaprio was not. Indications are that this is the case, seeing as how she's now married and expecting her first child with football star Tom Brady.