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Willa Holland, 'Arrow'

Holland stole the spotlight from her on-screen older sibling when she played Kaitlyn Cooper on "The O.C." -- and we think she's got it in her to win CW audiences over, too. Look out for her as Oliver Queen's pill-popping kid sister Thea when "Arrow" premieres on Wednesday, Oct. 10 at 8 p.m.... Getty Images
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