Matt Bomer

"White Collar" (USA) Bomer has been around for a while -- "Tru Calling" and the orphaned ABC show "Traveler" are on his resume, and he's been an important part of "Chuck" as superspy Bryce Larkin. But he gets to step to the forefront with USA's new show "White Collar," and it suits him well. Bomer has charm to spare playing a con man who switches sides and starts working for the FBI. "White Collar" may not be the best show of the fall, but Bomer helps make it very watchable. Related: Zap2it's Fall TV Preview
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